Visible‐Light Promoted Radical Fluoroalkylation of O‐ and N‐Substituted Alkenes

Visible‐Light Promoted Radical Fluoroalkylation of O‐ and N‐Substituted Alkenes Full article

Journal

Chemical Record
ISSN: 1527-8999 , E-ISSN: 1528-0691

Output data

Year: 2023, Volume: 23, Number: 9, Article number : e202300038, Pages count : DOI: 10.1002/tcr.202300038

Authors

Levin Vitalij V ¹ , Dilman Alexander D ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russian Federation

Interaction of enol ethers enol acetates, enamides and enamines with fluorinated reagents may be considered as a reliable method for the synthesis of organofluorine compounds. While classic nucleophile/electrophile substitution or addition mechanisms cannot be realized for coupling of these components, their intrinsic reactivities are revealed with the aid of photoredox catalysis. A combination of these electron donating and accepting components provides a perfect balance needed for individual redox steps, which in some cases may proceed even without a photocatalyst. The same electronic factors also support the key C,C-bond forming event involving addition of fluorinated radical at the electron rich double bond.

Levin V.V. , Dilman A.D.
Visible‐Light Promoted Radical Fluoroalkylation of O‐ and N‐Substituted Alkenes
Chemical Record. 2023. V.23. N9. e202300038 . DOI: 10.1002/tcr.202300038 WOS Scopus OpenAlex

Web of science:	WOS:000963045400001
Scopus:	2-s2.0-85151544522
OpenAlex:	W4362602300

DB	Citing
OpenAlex	6
Scopus	4
Web of science	5