Electrooxidative coupling of salts of nitro compounds with halide, nitrite, cyanide, and phenylsulfinate anions Научная публикация
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Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285 |
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| Вых. Данные | Год: 2005, Том: 54, Номер: 7, Страницы: 1585-1592 Страниц : 8 DOI: 10.1007/s11172-006-0007-7 | ||
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Реферат:
Electrolysis of salts of primary and secondary nitro compounds (nitroethane, 1- and 2-nitropropanes, nitrocyclohexane, and nitrocycloheptane) in the presence of excess halide, nitrite, cyanide, and phenylsulfinate anions under undivided and divided amperostatic electrolysis conditions in a two-phase medium (CH2Cl2/H2O) produces geminal nitrohalides (35–85% yields), dinitro compounds (15–51%), nitronitriles (6–27%), and nitrosulfones (50–70%). The salts of secondary nitro compounds form the products of oxidative coupling with halide and phenylsulfinate anions under the undivided electrolysis conditions. In all other cases, divided electrolysis is required.
Библиографическая ссылка:
Ilovaisky A.I.
, Merkulova V.M.
, Ogibin Y.N.
, Nikishin G.I.
Electrooxidative coupling of salts of nitro compounds with halide, nitrite, cyanide, and phenylsulfinate anions
Russian Chemical Bulletin. 2005. V.54. N7. P.1585-1592. DOI: 10.1007/s11172-006-0007-7 WOS Scopus OpenAlex
Electrooxidative coupling of salts of nitro compounds with halide, nitrite, cyanide, and phenylsulfinate anions
Russian Chemical Bulletin. 2005. V.54. N7. P.1585-1592. DOI: 10.1007/s11172-006-0007-7 WOS Scopus OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000234790700007 |
| Scopus: | 2-s2.0-31344470243 |
| OpenAlex: | W1970375953 |