Electrooxidative coupling of salts of nitro compounds with halide, nitrite, cyanide, and phenylsulfinate anions

Electrooxidative coupling of salts of nitro compounds with halide, nitrite, cyanide, and phenylsulfinate anions Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2005, Volume: 54, Number: 7, Pages: 1585-1592 Pages count : 8 DOI: 10.1007/s11172-006-0007-7

Authors

Ilovaisky A.I. ¹ , Merkulova V.M. ¹ , Ogibin Yu.N. ¹ , Nikishin G.I. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Electrolysis of salts of primary and secondary nitro compounds (nitroethane, 1- and 2-nitropropanes, nitrocyclohexane, and nitrocycloheptane) in the presence of excess halide, nitrite, cyanide, and phenylsulfinate anions under undivided and divided amperostatic electrolysis conditions in a two-phase medium (CH2Cl2/H2O) produces geminal nitrohalides (35–85% yields), dinitro compounds (15–51%), nitronitriles (6–27%), and nitrosulfones (50–70%). The salts of secondary nitro compounds form the products of oxidative coupling with halide and phenylsulfinate anions under the undivided electrolysis conditions. In all other cases, divided electrolysis is required.

Ilovaisky A.I. , Merkulova V.M. , Ogibin Y.N. , Nikishin G.I.
Electrooxidative coupling of salts of nitro compounds with halide, nitrite, cyanide, and phenylsulfinate anions
Russian Chemical Bulletin. 2005. V.54. N7. P.1585-1592. DOI: 10.1007/s11172-006-0007-7 WOS Scopus OpenAlex

Web of science:	WOS:000234790700007
Scopus:	2-s2.0-31344470243
OpenAlex:	W1970375953

DB	Citing
OpenAlex	4
Scopus	6
Web of science	5