Practical photocatalytic hydroalkylation of alkenes with chloroacetates mediated by formate ion

Practical photocatalytic hydroalkylation of alkenes with chloroacetates mediated by formate ion Научная публикация

Журнал

Organic chemistry frontiers
ISSN: 2052-4110 , E-ISSN: 2052-4129

Вых. Данные

Год: 2024, Том: 11, Номер: 10, Страницы: 2829-2833 Страниц : 5 DOI: 10.1039/d4qo00228h

Авторы

Malakhova Ekaterina V. ^1,2 , Kostromitin Vladislav S. ^3,2 , Levin Vitalij V. ² , Alexander Dilman ²

Организации

1	Higher Chemical College, D. Mendeleev University of Chemical Technology of Russia, Miusskaya sq. 9, 125047 Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation
3	Lomonosov Moscow State University, Department of Chemistry, Leninskie Gory 1-3, 119991 Moscow, Russian Federation

Processes that use commodity chemicals as substrates and reagents and that result in the formation of the C,C bond are highly desirable. Herein, a method for the radical alkylation of simple alkenes with readily available derivatives of chloracetic acid is described. Sodium formate serves as a stoichiometric reducing agent, and an organic cyanoarene type photocatalyst is used under blue light irradiation.

Malakhova E.V. , Kostromitin V.S. , Levin V.V. , Alexander Dilman
Practical photocatalytic hydroalkylation of alkenes with chloroacetates mediated by formate ion
Organic chemistry frontiers. 2024. V.11. N10. P.2829-2833. DOI: 10.1039/d4qo00228h Scopus OpenAlex

Scopus:	2-s2.0-85189014440
OpenAlex:	W4393105143

БД	Цитирований
OpenAlex	1
Scopus	2