Practical photocatalytic hydroalkylation of alkenes with chloroacetates mediated by formate ion

Practical photocatalytic hydroalkylation of alkenes with chloroacetates mediated by formate ion Full article

Journal

Organic chemistry frontiers
ISSN: 2052-4110 , E-ISSN: 2052-4129

Output data

Year: 2024, Volume: 11, Number: 10, Pages: 2829-2833 Pages count : 5 DOI: 10.1039/d4qo00228h

Authors

Malakhova Ekaterina V. ^1,2 , Kostromitin Vladislav S. ^3,2 , Levin Vitalij V. ² , Alexander Dilman ²

Affiliations

1	Higher Chemical College, D. Mendeleev University of Chemical Technology of Russia, Miusskaya sq. 9, 125047 Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation
3	Lomonosov Moscow State University, Department of Chemistry, Leninskie Gory 1-3, 119991 Moscow, Russian Federation

Processes that use commodity chemicals as substrates and reagents and that result in the formation of the C,C bond are highly desirable. Herein, a method for the radical alkylation of simple alkenes with readily available derivatives of chloracetic acid is described. Sodium formate serves as a stoichiometric reducing agent, and an organic cyanoarene type photocatalyst is used under blue light irradiation.

Malakhova E.V. , Kostromitin V.S. , Levin V.V. , Alexander Dilman
Practical photocatalytic hydroalkylation of alkenes with chloroacetates mediated by formate ion
Organic chemistry frontiers. 2024. V.11. N10. P.2829-2833. DOI: 10.1039/d4qo00228h Scopus OpenAlex

Scopus:	2-s2.0-85189014440
OpenAlex:	W4393105143

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OpenAlex	1
Scopus	2