One-Step Transformation of Aryl Diazonium Salts into Aryl Indium(III) Reagents Научная публикация
Журнал |
Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052 |
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Вых. Данные | Год: 2024, Том: 26, Номер: 21, Страницы: 4537-4541 Страниц : 5 DOI: 10.1021/acs.orglett.4c01448 | ||
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Реферат:
A method for the conversion of diazonium salts into intrinsically nucleophilic aryl indium reagents is described. The reaction is performed using indium(I) bromide with the C–In bond being formed by the interaction of aryl radicals with the indium salt. The obtained aryl indium(III) reagents work well in the Liebeskind–Srogl cross-coupling with thioesters, affording a wide variety of aryl ketones. This two-step transformation is a general method for the acylation of diazonium salts.
Библиографическая ссылка:
Supranovich V.I.
, Levin V.V.
, Dilman A.D.
One-Step Transformation of Aryl Diazonium Salts into Aryl Indium(III) Reagents
Organic Letters. 2024. V.26. N21. P.4537-4541. DOI: 10.1021/acs.orglett.4c01448 Scopus OpenAlex
One-Step Transformation of Aryl Diazonium Salts into Aryl Indium(III) Reagents
Organic Letters. 2024. V.26. N21. P.4537-4541. DOI: 10.1021/acs.orglett.4c01448 Scopus OpenAlex
Идентификаторы БД:
Scopus: | 2-s2.0-85193978636 |
OpenAlex: | W4398160386 |
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