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One-Step Transformation of Aryl Diazonium Salts into Aryl Indium(III) Reagents Научная публикация

Журнал Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052
Вых. Данные Год: 2024, Том: 26, Номер: 21, Страницы: 4537-4541 Страниц : 5 DOI: 10.1021/acs.orglett.4c01448
Авторы Supranovich Vyacheslav I. 1 , Levin Vitalij V. 1 , Dilman Alexander D. 1
Организации
1 N. D. Zelinsky Institute of Organic Chemistry, Leninsky Prospekt 47, 119991 Moscow, Russian Federation

Реферат: A method for the conversion of diazonium salts into intrinsically nucleophilic aryl indium reagents is described. The reaction is performed using indium(I) bromide with the C–In bond being formed by the interaction of aryl radicals with the indium salt. The obtained aryl indium(III) reagents work well in the Liebeskind–Srogl cross-coupling with thioesters, affording a wide variety of aryl ketones. This two-step transformation is a general method for the acylation of diazonium salts.
Библиографическая ссылка: Supranovich V.I. , Levin V.V. , Dilman A.D.
One-Step Transformation of Aryl Diazonium Salts into Aryl Indium(III) Reagents
Organic Letters. 2024. V.26. N21. P.4537-4541. DOI: 10.1021/acs.orglett.4c01448 WOS Scopus OpenAlex
Идентификаторы БД:
Web of science: WOS:001228923300001
Scopus: 2-s2.0-85193978636
OpenAlex: W4398160386
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БД Цитирований
OpenAlex 1
Web of science 1
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