One-Step Transformation of Aryl Diazonium Salts into Aryl Indium(III) Reagents

One-Step Transformation of Aryl Diazonium Salts into Aryl Indium(III) Reagents Full article

Journal

Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052

Output data

Year: 2024, Volume: 26, Number: 21, Pages: 4537-4541 Pages count : 5 DOI: 10.1021/acs.orglett.4c01448

Authors

Supranovich Vyacheslav I. ¹ , Levin Vitalij V. ¹ , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Leninsky Prospekt 47, 119991 Moscow, Russian Federation

A method for the conversion of diazonium salts into intrinsically nucleophilic aryl indium reagents is described. The reaction is performed using indium(I) bromide with the C–In bond being formed by the interaction of aryl radicals with the indium salt. The obtained aryl indium(III) reagents work well in the Liebeskind–Srogl cross-coupling with thioesters, affording a wide variety of aryl ketones. This two-step transformation is a general method for the acylation of diazonium salts.

Supranovich V.I. , Levin V.V. , Dilman A.D.
One-Step Transformation of Aryl Diazonium Salts into Aryl Indium(III) Reagents
Organic Letters. 2024. V.26. N21. P.4537-4541. DOI: 10.1021/acs.orglett.4c01448 Scopus OpenAlex

Scopus:	2-s2.0-85193978636
OpenAlex:	W4398160386

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