One-Step Transformation of Aryl Diazonium Salts into Aryl Indium(III) Reagents Full article
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Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052 |
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| Output data | Year: 2024, Volume: 26, Number: 21, Pages: 4537-4541 Pages count : 5 DOI: 10.1021/acs.orglett.4c01448 | ||
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Abstract:
A method for the conversion of diazonium salts into intrinsically nucleophilic aryl indium reagents is described. The reaction is performed using indium(I) bromide with the C–In bond being formed by the interaction of aryl radicals with the indium salt. The obtained aryl indium(III) reagents work well in the Liebeskind–Srogl cross-coupling with thioesters, affording a wide variety of aryl ketones. This two-step transformation is a general method for the acylation of diazonium salts.
Cite:
Supranovich V.I.
, Levin V.V.
, Dilman A.D.
One-Step Transformation of Aryl Diazonium Salts into Aryl Indium(III) Reagents
Organic Letters. 2024. V.26. N21. P.4537-4541. DOI: 10.1021/acs.orglett.4c01448 WOS Scopus OpenAlex
One-Step Transformation of Aryl Diazonium Salts into Aryl Indium(III) Reagents
Organic Letters. 2024. V.26. N21. P.4537-4541. DOI: 10.1021/acs.orglett.4c01448 WOS Scopus OpenAlex
Identifiers:
| Web of science: | WOS:001228923300001 |
| Scopus: | 2-s2.0-85193978636 |
| OpenAlex: | W4398160386 |