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Electrooxidative transformation of unsubstituted and substituted nitro hydrocarbons into carbonyl compounds Научная публикация

Журнал Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285
Вых. Данные Год: 2002, Том: 51, Номер: 8, Страницы: 1460-1465 Страниц : 6 DOI: 10.1023/a:1020906805561
Авторы Ogibin Yu.N. 1 , Ilovaiskii A.I. 1 , Merkulova V.M. 1 , Terent"ev A.O. 1 , Nikishin G.I. 1
Организации
1 Russian Academy of Sciences, N. D. Zelinsky Institute of Organic Chemistry, 47 Leninsky prosp., 119991, Moscow, Russian Federation

Реферат: Alkaline salts of aci-forms of secondary nitro compounds, viz., β-nitropropylbenzene, nitrocyclohexane, 5-nitroheptan-2-one, and methyl-4-nitrohexanoate, were selectively or predominately oxidized into the corresponding ketones and their ketals under conditions of undivided amperostatic electrolysis in methanol. Mixtures of the corresponding aldehydes, their acetals, and methyl carboxylates were formed under similar conditions from the salts of primary nitro compounds, viz., 1-nitrohexane, nitromethylbenzene, and β-nitroethylbenzene.
Библиографическая ссылка: Ogibin Y.N. , Ilovaiskii A.I. , Merkulova V.M. , Terent"ev A.O. , Nikishin G.I.
Electrooxidative transformation of unsubstituted and substituted nitro hydrocarbons into carbonyl compounds
Russian Chemical Bulletin. 2002. V.51. N8. P.1460-1465. DOI: 10.1023/a:1020906805561 Scopus OpenAlex
Идентификаторы БД:
Scopus: 2-s2.0-0036429781
OpenAlex: W2950497924
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