Electrooxidative transformation of unsubstituted and substituted nitro hydrocarbons into carbonyl compounds

Electrooxidative transformation of unsubstituted and substituted nitro hydrocarbons into carbonyl compounds Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2002, Volume: 51, Number: 8, Pages: 1460-1465 Pages count : 6 DOI: 10.1023/a:1020906805561

Authors

Ogibin Yu.N. ¹ , Ilovaiskii A.I. ¹ , Merkulova V.M. ¹ , Terent"ev A.O. ¹ , Nikishin G.I. ¹

Affiliations

1	Russian Academy of Sciences, N. D. Zelinsky Institute of Organic Chemistry, 47 Leninsky prosp., 119991, Moscow, Russian Federation

Alkaline salts of aci-forms of secondary nitro compounds, viz., β-nitropropylbenzene, nitrocyclohexane, 5-nitroheptan-2-one, and methyl-4-nitrohexanoate, were selectively or predominately oxidized into the corresponding ketones and their ketals under conditions of undivided amperostatic electrolysis in methanol. Mixtures of the corresponding aldehydes, their acetals, and methyl carboxylates were formed under similar conditions from the salts of primary nitro compounds, viz., 1-nitrohexane, nitromethylbenzene, and β-nitroethylbenzene.

Ogibin Y.N. , Ilovaiskii A.I. , Merkulova V.M. , Terent"ev A.O. , Nikishin G.I.
Electrooxidative transformation of unsubstituted and substituted nitro hydrocarbons into carbonyl compounds
Russian Chemical Bulletin. 2002. V.51. N8. P.1460-1465. DOI: 10.1023/a:1020906805561 Scopus OpenAlex

Scopus:	2-s2.0-0036429781
OpenAlex:	W2950497924

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