Complexes of Borane and 1,3,5‐Triazinane‐Derived Carbenes | Sciact

Complexes of Borane and 1,3,5‐Triazinane‐Derived Carbenes Научная публикация

Журнал

Advanced Synthesis & Catalysis
ISSN: 1615-4169 , E-ISSN: 1615-4150

Вых. Данные

Год: 2024, Том: 366, Номер: 11, Страницы: 2483-2488 Страниц : 6 DOI: 10.1002/adsc.202400122

Авторы

Smirnov Vladimir O. ¹ , Levin Vitalij V. ¹ , Dilman Alexander D. ¹

Организации

1	N. D. Zelinsky Institute of Organic Chemistry 119991 Moscow Leninsky prosp. 47 Russian Federation

Complexes of borane with six-membered N-heterocyclic carbenes derived from readily accessible 1,3,5-triazinium salts are described. Similar to the widely used imidazolium-type borane complex, the obtained complexes behave as agents for the hydrogen atom transfer in the Giese reaction and as sources of the boryl radicals in addition to imines. The amine nitrogen of these complexes does not undergo alkylation, but it can bind with another borane molecule.

Smirnov V.O. , Levin V.V. , Dilman A.D.
Complexes of Borane and 1,3,5‐Triazinane‐Derived Carbenes
Advanced Synthesis & Catalysis. 2024. V.366. N11. P.2483-2488. DOI: 10.1002/adsc.202400122 WOS Scopus OpenAlex

Web of science:	WOS:001216812700001
Scopus:	2-s2.0-85191696593
OpenAlex:	W4394723958

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