Complexes of Borane and 1,3,5‐Triazinane‐Derived Carbenes

Complexes of Borane and 1,3,5‐Triazinane‐Derived Carbenes Full article

Journal

Advanced Synthesis & Catalysis
ISSN: 1615-4169 , E-ISSN: 1615-4150

Output data

Year: 2024, Volume: 366, Number: 11, Pages: 2483-2488 Pages count : 6 DOI: 10.1002/adsc.202400122

Authors

Smirnov Vladimir O. ¹ , Levin Vitalij V. ¹ , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry 119991 Moscow Leninsky prosp. 47 Russian Federation

Complexes of borane with six-membered N-heterocyclic carbenes derived from readily accessible 1,3,5-triazinium salts are described. Similar to the widely used imidazolium-type borane complex, the obtained complexes behave as agents for the hydrogen atom transfer in the Giese reaction and as sources of the boryl radicals in addition to imines. The amine nitrogen of these complexes does not undergo alkylation, but it can bind with another borane molecule.

Smirnov V.O. , Levin V.V. , Dilman A.D.
Complexes of Borane and 1,3,5‐Triazinane‐Derived Carbenes
Advanced Synthesis & Catalysis. 2024. V.366. N11. P.2483-2488. DOI: 10.1002/adsc.202400122 Scopus OpenAlex

Scopus:	2-s2.0-85191696593
OpenAlex:	W4394723958

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