Silylation as a new strategy of the use of aliphatic nitro compounds in organic synthesis Научная публикация
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Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285 |
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| Вых. Данные | Год: 2001, Том: 50, Номер: 11, Страницы: 1936-1948 Страниц : 13 DOI: 10.1023/a:1015056024675 | ||
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Реферат:
Silylation of aliphatic nitro compounds is considered as a versatile multistage process. Due to activation of the β- and γ-carbon atoms of the initial nitro substrates, these reactions give rise to a series of products untypical of the traditional chemistry of nitro compounds. A new redox process proposed in the present study involves controlled incomplete reduction of the nitro group with simultaneous oxidation of the carbon skeleton of the initial aliphatic nitro compound.
Библиографическая ссылка:
Tartakovsky V.A.
, Ioffe S.L.
, Dilman A.D.
, Tishkov A.A.
Silylation as a new strategy of the use of aliphatic nitro compounds in organic synthesis
Russian Chemical Bulletin. 2001. V.50. N11. P.1936-1948. DOI: 10.1023/a:1015056024675 Scopus OpenAlex
Silylation as a new strategy of the use of aliphatic nitro compounds in organic synthesis
Russian Chemical Bulletin. 2001. V.50. N11. P.1936-1948. DOI: 10.1023/a:1015056024675 Scopus OpenAlex
Идентификаторы БД:
| Scopus: | 2-s2.0-0035541759 |
| OpenAlex: | W2952494721 |