Silylation as a new strategy of the use of aliphatic nitro compounds in organic synthesis

Silylation as a new strategy of the use of aliphatic nitro compounds in organic synthesis Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2001, Volume: 50, Number: 11, Pages: 1936-1948 Pages count : 13 DOI: 10.1023/a:1015056024675

Authors

Tartakovsky V.A. ¹ , Ioffe S.L. ¹ , Dilman A.D. ¹ , Tishkov A.A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

Silylation of aliphatic nitro compounds is considered as a versatile multistage process. Due to activation of the β- and γ-carbon atoms of the initial nitro substrates, these reactions give rise to a series of products untypical of the traditional chemistry of nitro compounds. A new redox process proposed in the present study involves controlled incomplete reduction of the nitro group with simultaneous oxidation of the carbon skeleton of the initial aliphatic nitro compound.

Tartakovsky V.A. , Ioffe S.L. , Dilman A.D. , Tishkov A.A.
Silylation as a new strategy of the use of aliphatic nitro compounds in organic synthesis
Russian Chemical Bulletin. 2001. V.50. N11. P.1936-1948. DOI: 10.1023/a:1015056024675 WOS Scopus OpenAlex

Web of science:	WOS:000175056400004
Scopus:	2-s2.0-0035541759
OpenAlex:	W2952494721

DB	Citing
OpenAlex	13
Scopus	17
Web of science	19