Silylation as a new strategy of the use of aliphatic nitro compounds in organic synthesis Full article
| Journal |
Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285 |
||
|---|---|---|---|
| Output data | Year: 2001, Volume: 50, Number: 11, Pages: 1936-1948 Pages count : 13 DOI: 10.1023/a:1015056024675 | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
Silylation of aliphatic nitro compounds is considered as a versatile multistage process. Due to activation of the β- and γ-carbon atoms of the initial nitro substrates, these reactions give rise to a series of products untypical of the traditional chemistry of nitro compounds. A new redox process proposed in the present study involves controlled incomplete reduction of the nitro group with simultaneous oxidation of the carbon skeleton of the initial aliphatic nitro compound.
Cite:
Tartakovsky V.A.
, Ioffe S.L.
, Dilman A.D.
, Tishkov A.A.
Silylation as a new strategy of the use of aliphatic nitro compounds in organic synthesis
Russian Chemical Bulletin. 2001. V.50. N11. P.1936-1948. DOI: 10.1023/a:1015056024675 Scopus OpenAlex
Silylation as a new strategy of the use of aliphatic nitro compounds in organic synthesis
Russian Chemical Bulletin. 2001. V.50. N11. P.1936-1948. DOI: 10.1023/a:1015056024675 Scopus OpenAlex
Identifiers:
| Scopus: | 2-s2.0-0035541759 |
| OpenAlex: | W2952494721 |