Fluoroalkyl sulfides as photoredox-active coupling reagents for alkene difunctionalization

Fluoroalkyl sulfides as photoredox-active coupling reagents for alkene difunctionalization Научная публикация

Журнал

Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X

Вых. Данные

Год: 2020, Том: 56, Номер: 66, Страницы: 9453-9456 Страниц : 4 DOI: 10.1039/d0cc04617e

Авторы

Kosobokov Mikhail D. ¹ , Zubkov Mikhail O. ¹ , Levin Vitalij V. ¹ , Kokorekin Vladimir A. ¹ , Dilman Alexander D. ¹

Организации

1	N. D. Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russian Federation

A visible-light-promoted fluoroalkylation-thiolation of alkenes is described. A 4-tetrafluoropyridinylthio fragment serves as a photoredox-active group in the initiation step and undergoes a radical group transfer, which is important for the reaction efficiency. In the primary products, the pyridinylthio substituent may be further functionalized via radical processes or an aromatic substitution reaction.

Kosobokov M.D. , Zubkov M.O. , Levin V.V. , Kokorekin V.A. , Dilman A.D.
Fluoroalkyl sulfides as photoredox-active coupling reagents for alkene difunctionalization
Chemical Communications. 2020. V.56. N66. P.9453-9456. DOI: 10.1039/d0cc04617e WOS Scopus OpenAlex

Web of science:	WOS:000560564400003
Scopus:	2-s2.0-85089712598
OpenAlex:	W3041011512

БД	Цитирований
OpenAlex	39
Scopus	37
Web of science	35