Fluoroalkyl sulfides as photoredox-active coupling reagents for alkene difunctionalization

Fluoroalkyl sulfides as photoredox-active coupling reagents for alkene difunctionalization Full article

Journal

Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X

Output data

Year: 2020, Volume: 56, Number: 66, Pages: 9453-9456 Pages count : 4 DOI: 10.1039/d0cc04617e

Authors

Kosobokov Mikhail D. ¹ , Zubkov Mikhail O. ¹ , Levin Vitalij V. ¹ , Kokorekin Vladimir A. ¹ , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russian Federation

A visible-light-promoted fluoroalkylation-thiolation of alkenes is described. A 4-tetrafluoropyridinylthio fragment serves as a photoredox-active group in the initiation step and undergoes a radical group transfer, which is important for the reaction efficiency. In the primary products, the pyridinylthio substituent may be further functionalized via radical processes or an aromatic substitution reaction.

Kosobokov M.D. , Zubkov M.O. , Levin V.V. , Kokorekin V.A. , Dilman A.D.
Fluoroalkyl sulfides as photoredox-active coupling reagents for alkene difunctionalization
Chemical Communications. 2020. V.56. N66. P.9453-9456. DOI: 10.1039/d0cc04617e WOS Scopus OpenAlex

Web of science:	WOS:000560564400003
Scopus:	2-s2.0-85089712598
OpenAlex:	W3041011512

DB	Citing
OpenAlex	48
Scopus	37
Web of science	40