The mechanism of CC bond formation on the Pt(IV) center involving chelate metallocycle ligands

The mechanism of CC bond formation on the Pt(IV) center involving chelate metallocycle ligands Научная публикация

Журнал

Journal of Organometallic Chemistry
ISSN: 1872-8561 , E-ISSN: 0022-328X

Вых. Данные

Год: 2000, Том: 604, Номер: 2, Страницы: 290-295 Страниц : 6 DOI: 10.1016/s0022-328x(00)00220-5

Авторы

Ananikov Valentine P ¹ , Mitchenko Sergey A ² , Beletskaya Irina P ³

Организации

1	N.D. Zelinsky Institute of Organic Chemistry, Leninsky Prospect 47, Moscow 117913, Russia
2	A.N. Nesmeyanov Institute of Organoelemental Compounds, Moscow 117813, Russia
3	M.V. Lomonosov Moscow State University, Moscow 119899, Russia

An unusual fact of CC reductive elimination reaction in bis-chelated Pt(IV) complexes under mild conditions was studied. It has been shown that breaking at least one of the chelate rings is required to promote a carboncarbon bond formation reaction. An intermediate complex, which resulted from a chelate ligand breaking process, was detected directly in the reaction mixture using 2D 1H–195Pt heteronuclear NMR spectroscopy.

Ananikov V.P. , Mitchenko S.A. , Beletskaya I.P.
The mechanism of CC bond formation on the Pt(IV) center involving chelate metallocycle ligands
Journal of Organometallic Chemistry. 2000. V.604. N2. P.290-295. DOI: 10.1016/s0022-328x(00)00220-5 Scopus OpenAlex

Scopus:	2-s2.0-0001110957
OpenAlex:	W1966435038

БД	Цитирований
OpenAlex	15
Scopus	16