The mechanism of CC bond formation on the Pt(IV) center involving chelate metallocycle ligands

The mechanism of CC bond formation on the Pt(IV) center involving chelate metallocycle ligands Full article

Journal

Journal of Organometallic Chemistry
ISSN: 1872-8561 , E-ISSN: 0022-328X

Output data

Year: 2000, Volume: 604, Number: 2, Pages: 290-295 Pages count : 6 DOI: 10.1016/s0022-328x(00)00220-5

Authors

Ananikov Valentine P ¹ , Mitchenko Sergey A ² , Beletskaya Irina P ³

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, Leninsky Prospect 47, Moscow 117913, Russia
2	A.N. Nesmeyanov Institute of Organoelemental Compounds, Moscow 117813, Russia
3	M.V. Lomonosov Moscow State University, Moscow 119899, Russia

An unusual fact of CC reductive elimination reaction in bis-chelated Pt(IV) complexes under mild conditions was studied. It has been shown that breaking at least one of the chelate rings is required to promote a carboncarbon bond formation reaction. An intermediate complex, which resulted from a chelate ligand breaking process, was detected directly in the reaction mixture using 2D 1H–195Pt heteronuclear NMR spectroscopy.

Ananikov V.P. , Mitchenko S.A. , Beletskaya I.P.
The mechanism of CC bond formation on the Pt(IV) center involving chelate metallocycle ligands
Journal of Organometallic Chemistry. 2000. V.604. N2. P.290-295. DOI: 10.1016/s0022-328x(00)00220-5 Scopus OpenAlex

Scopus:	2-s2.0-0001110957
OpenAlex:	W1966435038

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OpenAlex	15
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