O-Dinitropyrazolylmethyl-containing diazenium-1,2-diolates. Synthesis and properties

O-Dinitropyrazolylmethyl-containing diazenium-1,2-diolates. Synthesis and properties Научная публикация

Журнал

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Вых. Данные

Год: 2024, Том: 73, Номер: 5, Страницы: 1352-1361 Страниц : 10 DOI: 10.1007/s11172-024-4253-3

Авторы

Smirnov G.A. ¹ , Vatsadze I.A. ¹ , Gerasimov A.M. ¹ , Shkineva T.K. ¹ , Suponitsky K.Yu. ¹ , Pivkina A.N. ² , Dalinger I.L. ¹

Организации

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
2	N. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 119991, Moscow, Russian Federation

The reaction of 1-chloromethoxy-3,3-dimethyltriaz-1-ene 2-oxide with dinitropyrazoles produced the corresponding dinitropyrazolylmethyl-containing diazenium-1,2-diolates, 1-[(dinitro-1H-pyrazol-1-yl)methoxy)]-3,3-dimethyltriaz-1-ene 2-oxides. The obtained compounds were characterized by 1H, 13C, and 14N NMR spectroscopy. The synthesized 3,4- and 3,5-dinitro derivatives were studied by X-ray diffraction. The densities and the decomposition onset temperatures of the new compounds were experimentally determined and their detonation parameters were calculated.

Smirnov G.A. , Vatsadze I.A. , Gerasimov A.M. , Shkineva T.K. , Suponitsky K.Y. , Pivkina A.N. , Dalinger I.L.
O-Dinitropyrazolylmethyl-containing diazenium-1,2-diolates. Synthesis and properties
Russian Chemical Bulletin. 2024. V.73. N5. P.1352-1361. DOI: 10.1007/s11172-024-4253-3 WOS Scopus OpenAlex

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