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The effect of electrolysis conditions on the oxidation of styrene in methanol Научная публикация

Журнал Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285
Вых. Данные Год: 1994, Том: 43, Номер: 9, Страницы: 1536-1540 Страниц : 5 DOI: 10.1007/bf00697143
Авторы Ogibin Yu.N. 1 , Ilovaiskii A.I. 1 , Nikishin G.I. 1
Организации
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Реферат: Anodic oxidation of styrene (1) in methanol and the effect of the anion of the supporting electrolyte and of the anode material on this process have been studied. The most efficient conversion of1 into (1,2-dimethoxyethyl)benzene (2) occurs when the electrolysis is carried out with a platinum anode and with potassium fluoride or tetrabutylammonium tetrafluoroborate as the supporting electrolyte. Cleavage of the C-C σ bond in2 to give benzaldehyde dimethylacetal (3) is the most efficient at a graphite anode in the presence of sodium tosylate.
Библиографическая ссылка: Ogibin Y.N. , Ilovaiskii A.I. , Nikishin G.I.
The effect of electrolysis conditions on the oxidation of styrene in methanol
Russian Chemical Bulletin. 1994. V.43. N9. P.1536-1540. DOI: 10.1007/bf00697143 WOS Scopus OpenAlex
Идентификаторы БД:
≡ Web of science: WOS:A1994QP24800021
≡ Scopus: 2-s2.0-0040923824
≡ OpenAlex: W2952898292
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