The effect of electrolysis conditions on the oxidation of styrene in methanol

The effect of electrolysis conditions on the oxidation of styrene in methanol Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 1994, Volume: 43, Number: 9, Pages: 1536-1540 Pages count : 5 DOI: 10.1007/bf00697143

Authors

Ogibin Yu.N. ¹ , Ilovaiskii A.I. ¹ , Nikishin G.I. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Anodic oxidation of styrene (1) in methanol and the effect of the anion of the supporting electrolyte and of the anode material on this process have been studied. The most efficient conversion of1 into (1,2-dimethoxyethyl)benzene (2) occurs when the electrolysis is carried out with a platinum anode and with potassium fluoride or tetrabutylammonium tetrafluoroborate as the supporting electrolyte. Cleavage of the C-C σ bond in2 to give benzaldehyde dimethylacetal (3) is the most efficient at a graphite anode in the presence of sodium tosylate.

Ogibin Y.N. , Ilovaiskii A.I. , Nikishin G.I.
The effect of electrolysis conditions on the oxidation of styrene in methanol
Russian Chemical Bulletin. 1994. V.43. N9. P.1536-1540. DOI: 10.1007/bf00697143 WOS Scopus OpenAlex

Web of science:	WOS:A1994QP24800021
Scopus:	2-s2.0-0040923824
OpenAlex:	W2952898292

DB	Citing
OpenAlex	14
Scopus	15
Web of science	15