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Electrochemical cleavage of the double bond of 1-alkenylarenes Научная публикация

Журнал Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230
Вых. Данные Год: 1991, Том: 40, Номер: 3, Страницы: 561-566 Страниц : 6 DOI: 10.1007/bf00957996
Авторы Ogibin Yu.N. 1 , Sokolov A.B. 1 , Ilovaiskii A.I. 1 , Elinson M.N. 1 , Nikishin G.I. 1
Организации
1 N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

Реферат: A study has been made of the electrochemical cleavage of the double bond of propenylbenzene (Ia) and p-propenylanisole (Ib), which takes place upon anodic oxidation of (Ia, b) in alcoholic solutions of sodium trifluoroacetate and other electrolytes and which leads to conversion of (Ia, b) to benzaldehyde dialkylacetals. Conditions are found that provide for highly selective (>80%) conversion of (Ib) and p-propenyl toluene to p-methyl- and p- methoxybenzaldehyde dimethylacetals.
Библиографическая ссылка: Ogibin Y.N. , Sokolov A.B. , Ilovaiskii A.I. , Elinson M.N. , Nikishin G.I.
Electrochemical cleavage of the double bond of 1-alkenylarenes
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1991. V.40. N3. P.561-566. DOI: 10.1007/bf00957996 OpenAlex
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