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Electrochemical cleavage of the double bond of 1-alkenylarenes Full article

Journal Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230
Output data Year: 1991, Volume: 40, Number: 3, Pages: 561-566 Pages count : 6 DOI: 10.1007/bf00957996
Authors Ogibin Yu.N. 1 , Sokolov A.B. 1 , Ilovaiskii A.I. 1 , Elinson M.N. 1 , Nikishin G.I. 1
Affiliations
1 N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

Abstract: A study has been made of the electrochemical cleavage of the double bond of propenylbenzene (Ia) and p-propenylanisole (Ib), which takes place upon anodic oxidation of (Ia, b) in alcoholic solutions of sodium trifluoroacetate and other electrolytes and which leads to conversion of (Ia, b) to benzaldehyde dialkylacetals. Conditions are found that provide for highly selective (>80%) conversion of (Ib) and p-propenyl toluene to p-methyl- and p- methoxybenzaldehyde dimethylacetals.
Cite: Ogibin Y.N. , Sokolov A.B. , Ilovaiskii A.I. , Elinson M.N. , Nikishin G.I.
Electrochemical cleavage of the double bond of 1-alkenylarenes
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1991. V.40. N3. P.561-566. DOI: 10.1007/bf00957996 OpenAlex
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OpenAlex: W2952242011
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